A cyclopalladated complex of corannulene with a pyridine pendant and its columnar self-assembly.
نویسندگان
چکیده
Bowl-shaped corannulene provides various metal binding modes with its curved π-surfaces and rim. Herein, we report the syntheses of 2-pyridylcorannulene and its cyclopalladated complex. Its expanded π-system and columnar self-assembly in the crystal state were revealed by NMR and UV-vis spectroscopies, ESI-TOF mass spectrometry and single-crystal X-ray analysis.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 10 شماره
صفحات -
تاریخ انتشار 2013